Yes. User Profiles for Jira (Microsoft Attributes Sync) syncs the manager attribute from Entra ID (Azure AD) into Jira. You can then use it in Jira workflows and automation rules to route approval steps to the right manager. Once the workflow is set up, requests like purchase approvals, content sign-off, or contract reviews go to the correct approver without anyone assigning them by hand. This works in Jira and Jira Service Management.